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JOURNAL ARTICLE

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Preparation and Pb(II) Adsorption Properties of Crosslinked Pectin-Carboxymethyl Chitosan Film

Hastuti, Budi; Mudasir, Mudasir; Siswanta, Dwi; Triyono, Triyono

A modified pectin has been synthesized by reacting/combining -OH group among pectin and chitosan with BADGE (Bisphenol A diglycidyl ether) crosslinker agent. The structure and morphology of the new material were characterized by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and X-ray Diffraction (XRD) analysis. Thermogravimetric studies showed an improvement in thermal characteristic. Adsorption experiments were performed in batch processes; sorption isotherms and kinetics were also studied. The Langmuir and Freundlich adsorption isotherm models were applied to describe the isotherms and isotherm constants for the adsorption of Pb(II) ion onto adsorbent pectin-carboxymethyl chitosan-BADGE (pec-CMC-BADGE). The dynamic study showed that the sorption process followed the second-order kinetic equation. Result indicated also that Pb(II) ion uptake could be well described by the Langmuir and Freundlich adsorption model of pec-CMC-BADGE and CMC with DG° of 25.3 and 23.1 kJ mol-1,respectively, while that of pectin followed Freundlich isotherm with DG° of 16.6 kJ mol-1.

Informasi Detail
Journal
Indonesian Journal of Chemistry; Vol 15, No 3 (2015); 248-255
Penerbit
Universitas Gadjah Mada
Tahun Terbit
2015
Bahasa
eng
ISSN
-
DOI
10.22146/ijc.21192
License
http://creativecommons.org/licenses/by-nc-nd/4.0
Last Updated
2017-03-02T14:49:45Z
Subjek / Keywords
pectin carboxymethyl chitosan BADGE adsorption Pb(II)
Akses Artikel
Baca PDF Baca Fulltext Lihat di Jurnal DOI: 10.22146/ijc.21192
Info Journal

Indonesian Journal of Chemistry; Vol 15, No 3 (2015); 248-255

Penerbit: Universitas Gadjah Mada

Perpustakaan Sekolah Tinggi Ilmu Syariah Hidayatullah
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