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Methylation of Eugenol Using Dimethyl Carbonate and Bentonite as Catalyst

Asnawati, Dina; Sudarma, I Made; Yuanita, Emmy; Arlina, Baiq Fadila; Hamdiani, Saprini; Kamali, Siti Raudhatul

Eugenol is a compound with a variety of reactive functional groups such as allyl, hydroxy and methoxy. The presence of the functional groups brings eugenol possible to undertake the transformation into various derivative compounds with diverse activities. One of the simple and possible transformations is methylation or alkylation. Commonly, methyl halides and dimethyl sulphate are used as methylation agent. However, those kinds of methylation agents are toxic and carcinogenic. In this research dimethyl carbonate, an alternative methylation agent is used, because of its low toxicity, green, and economic. The synthesis has been carried out by using a catalyst. Bentonite was activated by heating to a temperature using 300 °C. Methylation was shown by the formation of a light yellow liquid (25.71% yield). The structures of products were characterized by GC-MS and obtained a compound, namely bis eugenol (4-allyl-2-methoxyphenoxy) methane (2.37% yield).

Informasi Detail
Journal
Indonesian Journal of Chemistry; Vol 15, No 3 (2015); 256-262
Penerbit
Universitas Gadjah Mada
Tahun Terbit
2015
Bahasa
eng
ISSN
-
DOI
10.22146/ijc.21193
License
http://creativecommons.org/licenses/by-nc-nd/4.0
Last Updated
2017-03-02T14:49:45Z
Subjek / Keywords
methyl eugenol bentonite dimethyl carbonate
Akses Artikel
Baca PDF Baca Fulltext Lihat di Jurnal DOI: 10.22146/ijc.21193
Info Journal

Indonesian Journal of Chemistry; Vol 15, No 3 (2015); 256-262

Penerbit: Universitas Gadjah Mada

Perpustakaan Sekolah Tinggi Ilmu Syariah Hidayatullah
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